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Comparison of oxygen permeation through some perovskite membranes synthesized with EDTNAD

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Abstract

Three dense membranes of types SrCo0.8Fe0.2O3−δ (SCF(82)), La0.6Sr0.4Co0.8Fe0.2O3−δ (LSCF(6482)) and La0.8Sr0.2Co0.6Fe0.4O3−δ (LSCF(8264)) perovskites were prepared by complexation applying a chelating agent, ethylene diamine N,N,N′,N′-tetra-N-acetyl-diamine (EDTNAD). The oxygen permeation flux through the perovskite membranes was measured as a function of temperature within 1,073–1,223 K as well as the oxygen partial pressure of 0.1–1.0 bar. The oxygen permeation fluxes for the membranes, SCF(82), LSCF(6482), LSCF(8264) with the thickness of 0.85 mm were observed as 9.2 × 10−7 (mol/cm2 s), 1.7 × 10−7 (mol/cm2 s), and 1.0 × 10−7 (mol/cm2 s) in these cases at 1,153 K. The results indicated the oxygen permeation process was mainly controlled by the oxygen bulk diffusion through these membranes.

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Acknowledgment

The financial support of the Research Institute of Petroleum Industry is gratefully acknowledged.

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Authors and Affiliations

  1. Research Institute of Petroleum Industry, P.O. Box 18745/4163, Tehran, Iran

    Z. Taheri, K. Nazari, N. Seyed-Matin, S. Zarrinpashne & R. Ahmadi

  2. Faculty of Chemical Engineering, Sharif University of Technology, Tehran, Iran

    A. A. Safekordi

  3. Faculty of Chemistry, Sharif University of Technology, Tehran, Iran

    B. Ghanbari

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  1. Z. Taheri
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  2. K. Nazari
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Correspondence to Z. Taheri.

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Taheri, Z., Nazari, K., Seyed-Matin, N. et al. Comparison of oxygen permeation through some perovskite membranes synthesized with EDTNAD. Reac Kinet Mech Cat 100, 459–469 (2010). https://doi.org/10.1007/s11144-010-0158-2

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